Microstructural and microchemical mechanisms controlling intergranular stress corrosion cracking in lightwaterreactor systems stephen m. Transgranular corrosion is also known as intragranular corrosion and transcrystalline corrosion. Intergranular stress corrosion cracking igscc of bwr internal components has been identified as a technical issue of concern by both the nrc staff and the industry. Intergranular stress corrosion cracking in rbmk reactors to assist countries operating rbmk reactors in addressing the issue in austenitic stainless steel 300 mm diameter piping. Decoupling the role of stress and corrosion in the. Proceedings of the 17th international conference on nuclear engineering. Transgranular stress corrosion cracking tgscc cracks run through the individual grains. In the presence of tensile stress, cracking may occur along grain boundaries and this type of corrosion is frequently called intergranular stress corrosion cracking igscc or simply intergranular corrosion cracking. Intergranular stress corrosion cracking igscc cracks propagate along the grain boundaries.
Pdf stress corrosion cracking scc of nickelbased alloys. Intergranular stress corrosion cracking igscc is the progressive nucleation and growth of cracks by localized corrosion along the grain boundaries in metals in the presence of stress or strain. A specific objective of this work was to predict the performance of alloy casting institute cf3, cf3a, and cf8 castings in nuclear applications. Mitigation of intergranular stress corrosion cracking in. Intergranular stress corrosion cracking resistance of. The general pattern of the observed failures indicates that as nuclear plants age and fluence increases, various apparently nonsensitized austenitic stainless steels. It is associated with the simultaneous presence of a number of factors. In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev.
Cracking in the heat affected zone of stainless steel piping due to chromium carbide formation at grain boundaries and chromium. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. Irradiationassisted stress corrosion cracking iascc is a form of intergranular stress corrosion cracking igscc that has occurred infrequently during the last two decades in incore components of nonsensitized austenitic stainless steel. Intergranular stress corrosion cracking growth behavior of nicrfe alloys in pressurized water reactor primary water.
The occurrences of intergranular stresscorrosion cracking in nuclear power plant components made of austenitic alloys are discussed. The intergranular stress corrosion cracking igscc growth behavior of austenitic stainless steels ss in hydrogenated hightemperature water were studied using compact tension specimens 0. Iaea nuclear energy series stress corrosion cracking in light. Intergranular stressassisted corrosion cracking of austenitic alloys. Laser peening is an emerging modern process that impresses a compressive stress into the surface of metals or alloys. This treatment can reduce the rate of intergranular stress corrosion cracking and fatigue cracking in structural metals or alloy 600 needed for nuclear power plants. Mitigation of intergranular stress corrosion cracking in rbmk reactors if you would like to learn more about the iaeas work, sign up for our weekly updates containing our most important news, multimedia and more. Structural reliability improvement using inservice inspection for. The iaea nuclear energy series complements the iaea safety standards.
Intergranular stress corrosion cracking igscc is stress corrosion cracking. One of the most serious metallurgical problems and one that is a major concern in the nuclear industry is stress corrosion cracking scc. Hydrogen and hydrazine coinjection to mitigate stress corrosion cracking of structural materials in boiling water reactors, vi the effect of ammonia on intergranular stress corrosion cracking. Mechanistic differences in transgranular and intergranular. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. Irradiationassisted stress corrosion cracking as a factor. This behavior indicates that percent intergranular stress corrosion cracking determined at. The core shroud is among the list of internals susceptible to igscc.
Iascc is apparently a timedependent phenomenon, which does not manifest itself until a minimum residence time or threshold fast neutron. Mitigation of intergranular stress corrosion cracking in rbmk reactors if you would like to learn more about the iaeas work, sign up for our weekly updates containing our. Bruemmer materials sciences department, pacific northwest laboratory, richland, wa 99352, usa gary s. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Here the reverse of segregationchromium depletionis responsible for accelerated oxidation and cracking in the intergranular regions. Delta phase is high in niobium and chemically different from the matrix. Durance, david, sedman, ken, roberts, john, and gorman, jeff. Another example of property degradation is seen in intergranular stress corrosion cracking in austenitic steels used in modern nuclear power plants. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Intergranular corrosion is sometimes also called intercrystalline corrosion or interdendritic corrosion. Intergranular stress corrosion cracking initiation model of.
Free intergranular stress corrosion and nuclear reactors essay. Major contributors to intergranular stress corrosion cracking in boiling water reactor nuclear power plants. Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack. The evaluation of intergranular stress corrosion cracking problems of stainless steel piping in taiwan bwr6 nuclear power plant.
Irradiationassisted stress corrosion cracking iascc is a form of intergranular stress corrosion cracking igscc that has occurred infrequently during t. Intergranular corrosion in nuclear systems astm international. Cracks of this type have occurred in sensitized types 304 and 316 austenitic stainless steels in a variety of components at various stages of fabrication. The first part of this chapter describes the stresscorrosion cracking model. Intergranular stress corrosion cracking igscc is a mode of subcritical crack propagation in susceptible nickelbased alloys and austenitic stainless steels used in power generation. Laser peening of alloy 600 to improve intergranular stress.
Stress corrosion cracking of current structural materials in. Austenitic stainless steels are susceptible to stress corrosion cracking scc in. The environmental and metallurgical factors in the intergranular stress corrosion cracking of austenitic stainless steel at temperatures below 100 c has been examined. Modelling intergranular stress corrosion cracking in. The evaluation of intergranular stress corrosion cracking. Irradiation assisted stress corrosion cracking iascc refers to intergranular stress corrosion cracking that is accelerated under the action of irradiation in light water reactor core components. Observations of intergranular stress corrosion cracking in. A calculation model on intergranular stress corrosion cracking igscc initiation time of. Effects of hydrogen peroxide on intergranular stress. Hydrogen and hydrazine coinjection to mitigate stress. After identification of the first assemblies susceptible of being affected by igscc, enusa has developed multidisciplinary actions to mitigate the impact in the strategy for dry storage and transportation. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. Intergranular stress corrosion cracking scc of pipelines has been known to cause pipeline failure since the 1960s and is associated with a high ph, above 9, in the electrolyte in direct contact with the external pipe surface.
Intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. Crack growth is driven by the inelastic deformation at the sharp crack tip. Chloride stress corrosion cracking clscc requires the presence of a residual or applied tensile stress and the presence of chloride ions under specific environmental conditions. The increased stress corrosion cracking resistance exhibited by the mht condition may be due to grain boundary homogeneity. Stress corrosion cracking of alloy 718 in pressurized. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. The effects of carbide precipitation, alloy composition, and the cold rolling direction on crack growth behavior were studied. For example, the low carbon austenitic stainless steels such as 316 nuclear. Stress corrosion cracking behavior of nickel base alloys. The uk currently operates a civil nuclear fleet consisting primarily of advanced gas reactors agrs, a pressurized water reactor pwr and a nuclear energy powered submarine fleet of pwrs. Scc is a type of intergranular attack corrosion that occurs at the grain boundaries under tensile stress.
Intergranular stress corrosion cracking of welded steel twi. The behavior of annealed and sensitized microstructures in a variety of environments, including oxygencontaining pure water and aqueous solutions containing species such as. Intergranular stress corrosion cracking igscc of austenitic stainless steels has been an important concern in nuclear power plants for many years. Intergranular stress corrosion cracking igscc is stress corrosion cracking where the grain boundaries of a susceptible material are cracked due to stress and an agressive environment. Stress corrosion cracking results from the combined action of an applied tensile stress and a corrosive environment, both influences are necessary.
Stress corrosion cracking can proceed in one of two ways. The mechanism of cracking in both these modes and the conditions under which the transition from tram to intergranular cracking or vice versa occur are topics of much debate and research, some recent work have suggested that the mechanism of trans and intergranular stress corrosion cracking are identical, in this study, by using the load. Why is chloride stress corrosion cracking transgranular. Investigation of stress corrosion cracking susceptibility. A mechanistic basis for irradiation assisted stress. Nonstabilized 300 series stainless steels stressed over yield are susceptible to intergranular stress corrosion cracking scc when exposed in the heavily sensitized condition to 288 c 550 f, high purity water containing dissolved oxygen. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Irradiationassisted stress corrosion cracking as a factor in nuclear. Stress corrosion cracking odonnell consulting engineers. Intergranular stressassisted corrosion cracking of austenitic alloys in water cooled nuclear reactors. Intergranular stress corrosion cracking igscc of austenitic stainless steels, usually aisi 304 steel, is a serious problem in boiling water reactors bwr.
Intergranular stress corrosion cracking igscc highly relates to the nucleation of cracks in the heat affected zonehaz or coldworked zone of austenitic stainless steels, especially in the cases of aged nuclear pressure reactor components1. Intergranular stress corrosion cracking an overview. Alloy b2 is damaged by intergranular stress corrosion cracking in the heat affected region when subjected to organic solvents comprising of sulfuric acid at 120oc. Stress corrosion cracking scc is a significant ageing degradation mechanism for major components of both pressurized water reactors pwrs and boiling water reactors bwrs. An arizona state university research team has released new insights about intergranular stresscorrosion cracking scc, an environmental cause of premature failure in engineered structures. Heat exchangers in commercial nuclear systems have shown scc in only a fraction of a percent of the tubes in high temperature water, but laboratory scc of nicontaining alloys have been demonstrated by several research groups. Intergranular stress corrosion cracking igscc is a form of environmentally induced crack propagation causing premature failure of elemental metals and alloys. Effects of irradiation on intergranular stress corrosion. T1 intergranular stress corrosion cracking of austenitic stainless steels. Decoupling stress and corrosion to predict metal failure. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. Intergranular corrosion igc, also known as intergranular attack iga, is a form of corrosion where the boundaries of crystallites of the material are more susceptible to corrosion than their insides. Review of the stress corrosion cracking of inconel 600. In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking.
Stress corrosion cracking scc of nickelbased alloys. Intergranular stress corrosion cracking of austenitic stainless steel piping in bwrs has. Advanced steels for accident tolerant fuel cladding in commercial nuclear. Intergranular stress corrosion cracking scc of inconel 600 is of concern to the nuclear power industry. Ultrasonic inspection reliability for intergranular stress. Effects of hydrogen peroxide on intergranular stress corrosion cracking of stainless steel in high temperature water, i journal of nuclear science and. Intergranular stress corrosion cracking of austenitic. Probabilistic failure analysis of nuclear piping of bwr plant was carried out by. Understanding the mechanisms controlling low potential.
There have been two major material factors that have. This paper evaluates the resistance to intergranular stresscorrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings. Intergranular stress corrosion cracking in nuclear power plants. Was deparrments of nuclear engineering and materials science and engineering, university of michigan, ann. Ffs issues for steam generator tube top of tubesheet intergranular attackstress corrosion cracking. Microstructural and microchemical mechanisms controlling.